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Learn the skill
For ordinary dry, room-temperature conditions, copper is a good conductor and plastic is a useful insulator. A wire can combine a metal core with a plastic covering. This does not make any damaged or unknown cable safe to touch. Study the picture, not real cables. Use pictures only. Never use wall outlets or put batteries in your mouth.
Worked example
The copper core carries current more readily than the plastic jacket. The jacket helps keep the conducting core separated from other things. Damaged cords need an adult's attention, not a student repair.