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Wind and Air: Compressible Gas Models

Use absolute pressure and temperature in ideal-gas comparisons.

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For a fixed amount of ideal gas, pV is proportional to absolute temperature T. At constant T, p1V1 = p2V2. Use absolute pressure, not gauge pressure, and kelvin temperature, not Celsius ratios. These are calculation models, not home pressure experiments.

Worked example

At fixed temperature, 2 L at 100 kPa absolute becomes 1 L at 200 kPa absolute. Halving the volume doubles pressure. Heating a rigid container from 300 K to 600 K also doubles absolute pressure if the amount of gas stays fixed.

The same amount of ideal gas at the same temperature is shown at 2 liters and 100 kilopascals, then at 1 liter and 200 kilopascals. Boyle law keeps absolute pressure times volume constant.
The same amount of ideal gas at the same temperature is shown at 2 liters and 100 kilopascals, then at 1 liter and 200 kilopascals. Boyle law keeps absolute pressure times volume constant.
Question 1 At constant temperature, 2 L at 100 kPa is compressed to 1 L. Final pressure is what?
Question 2 Which pressure should be used in pV = nRT?
Question 3 At fixed volume and gas amount, 300 K becomes 600 K. Pressure changes by what factor?
Question 4 Why not substitute Celsius temperature ratios directly?
Question 5 What could invalidate the fixed-amount comparison?